东昆仑夏日哈木地区二长花岗岩年代学、地球化学特征及地质意义     

郭峰  王盘喜  卞孝东  冯乃琦 《中国地质调查》2020,7(6):51-60

东昆仑夏日哈木地区首次发现了早泥盆世二长花岗岩,对其开展年代学和地球化学特征研究,进一步探讨其岩石成因和构造地质背景。二长花岗岩锆石U-Pb年龄为(412.1±5.7) Ma(MSWD=0.95),形成于早泥盆世早期; 岩石为过弱铝质亚碱性花岗岩,富SiO₂(含量为71.41%~72.46%)、K₂O(含量为5.27%~6.16%),贫Fe₂O₃(含量为1.86%~2.05%)、P₂O₅(含量为0.08%~0.12%),富集轻稀土元素,具明显的负Eu异常; 在原始地幔标准化微量元素蛛网图上可以看出,岩石明显富集Rb、Th、Zr、Hf,强烈亏损Nb、Sr、P、Ti、Ba。夏日哈木地区二长花岗岩属于I型花岗岩,其源岩可能由幔源岩浆底侵加热下地壳岩石致其部分熔融而形成,处于由同碰撞向后碰撞转换的构造环境,说明东昆仑夏日哈木地区在早泥盆世早期已进入伸展阶段。  相似文献   

烃源岩不同性质有机酸的分离及其检测方法     

杜佳宗  何蓓  蔡进功  雷天柱  刘庆  谢忠怀 《高校地质学报》2020,26(5):540-548

烃源岩中的有机酸来源于有机质，但有机质具有不同的赋存形式，有机酸具有不同性质，这将影响有机酸与不同赋存有机质的关系，进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上，提出烃源岩中的有机酸并以非单一的形式存在，具有水溶性、脂溶性和难溶性有机酸三种类型，游离有机质中存在水溶性和脂溶性有机酸，而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法，且根据有机酸的性质选取合适的检测方法，即水溶性有机酸利用离子色谱检测，索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测，通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测，全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律，深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。  相似文献   

Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence     

《China Geology》2020,3(4):602-610

Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin, Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry. The bulk carbon isotopic values of the whole rock extracts, saturate and aromatic fractions range from –28.7‰ to –26.8‰, –29.2‰ to –27.2 ‰ and –28.5 ‰ to –26.7 ‰, respectively while the bulk carbon isotopic values of the whole oils, saturate and aromatic fractions range from –25.4 ‰ to –27.8 ‰, –25.9 ‰ to –28.4 ‰ and –23.5 ‰ to –26.9 ‰, respectively. The average carbon isotopic compositions of individual alkanes (nC₁₂-nC₃₃) in the rock samples range from –34.9‰ to –28.2‰ whereas the average isotopic values of individual n-alkanes in the oils range from –31.1‰ to –23.8‰. The δ¹³C isotope ratios of pristane and phytane in the rock samples range from –29.2 ‰ to –28.2 ‰ and –30.2 ‰ to –27.4 ‰ respectively while the pristane and phytane isotopic values range from –32.1‰ to –21.9‰ and –30.5‰ to –26.9‰, respectively. The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments. The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.  相似文献   

海拉尔—塔木察格盆地中部富油凹陷高含凝灰质碎屑岩储层成因及油气勘探意义     

蒙启安  李军辉  李跃  邹越 《吉林大学学报(地球科学版)》2020,50(2):569-578

海拉尔—塔木察格盆地中部富油凹陷下白垩统铜钵庙组和南屯组广泛发育高含凝灰质碎屑岩储层，并已于其中获得了工业突破，但对其成因机制认识不清。在岩心、薄片、录井和测井等资料综合研究的基础上，结合大量海拉尔—塔木察格盆地及周边地区的火山事件分析，认为中部富油凹陷发育的高含凝灰质碎屑岩的岩石类型主要包括凝灰质砂岩、凝灰质泥岩、凝灰岩和沉凝灰岩。不同时期、不同凹陷高含凝灰质碎屑岩储层发育特点各异，整体来看从铜钵庙组到南屯组储层中的凝灰质含量越来越低，高含凝灰质碎屑岩储层主要发育在铜钵庙组和南一段沉积时期。高含凝灰质碎屑岩储层中的火山物质并非来源于自身断陷期发生的基性火山活动，而是来自于大兴安岭地区大规模的酸性火山喷发事件。海拉尔—塔木察格盆地高含凝灰质碎屑岩储层的成因机制包括两种类型：一种是同沉积期火山灰直接空降入湖型；另一种是同沉积期火山灰先沉降至陆上经河流搬运后再沉积的水携型。高含凝灰质碎屑岩储层中的火山碎屑物质受有机酸作用易于溶蚀，次生孔隙发育，为深部油气成藏提供了有效储层空间，并且火山喷发活动对优质烃源岩的形成具有促进作用，对于油气勘探具有重要意义。  相似文献   

青藏高原凯蒙蛇绿混杂岩中碱性火山岩的发现及意义     

潘政  史仁灯  黄启帅  陈生生  龚小晗  吴钪  杨可 《岩石矿物学杂志》2020,39(1):18-34

班公湖-怒江洋的关闭时间直接制约青藏高原早期构造演化的认识。最近,在班公湖-怒江缝合带南侧凯蒙蛇绿混杂岩中发现一碱性火山岩,岩性主要是橄榄粗安岩,具粗面结构,斑晶主要是更长石和少量普通辉石,基质主要由更长石、普通辉石和少量填隙的碱性长石组成,有的具辉绿结构。岩石化学成分较一致,Si O2含量介于51.34%~53.91%之间,Ti O2含量为1.02%~1.55%,具有高Al2O3(17.06%~18.46%)和Na2O(4.90%~6.36%)、低K2O(0.05%~0.88%)含量特点,大多数Mg#大于60,最高68.62,里特曼指数(σ)介于3.65~4.47之间,为碱性系列火山岩;富集Sr、Rb、Ba等大离子亲石元素,亏损Nb、Y、Yb等高场强元素,相对富集Zr、Ti,Nb/U、Zr/Nb、La/Yb等比值稳定,分别为7.45~8.51、15.92~17.26和7.26~8.06;(87Sr/86Sr)i值变化范围较小,介于0.706~0.707之间,(143Nd/144Nd)t值在0.512 368~0.512 548之间,说明源区较为一致,结合Ce/Pb-Si O2图解判断结果,认为凯蒙碱性火山岩具有原始地幔、陆壳和深海沉积物源区混合特征。锆石U-Pb同位素定年结果表明该火山岩年龄为101.8±1.1 Ma,可能形成于洋壳俯冲阶段末期,由大陆边缘陆壳与俯冲洋壳板片断离导致软流圈地幔上涌诱发部分熔融所致,推测班公湖-怒江洋大约在早白垩世晚期关闭。  相似文献   

Phase equilibrium modelling of the amphibolite to granulite facies transition in metabasic rocks (Ivrea Zone,NW Italy)     

Barbara E. Kunz  Richard W. White 《Journal of Metamorphic Geology》2019,37(7):935-950

The development of thermodynamic models for tonalitic melt and the updated clinopyroxene and amphibole models now allow the use of phase equilibrium modelling to estimate P–T conditions and melt production for anatectic mafic and intermediate rock types at high‐T conditions. The Permian mid‐lower crustal section of the Ivrea Zone preserves a metamorphic field gradient from mid amphibolite facies to granulite facies, and thus records the onset of partial melting in metabasic rocks. Interlayered metabasic and metapelitic rocks allows the direct comparison of P–T estimates and partial melting between both rock types with the same metamorphic evolution. Pseudosections for metabasic compositions calculated in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (NCKFMASHTO) system are presented and compared with those of metapelitic rocks calculated with consistent end‐member data and a–x models. The results presented in this study show that P–T conditions obtained by phase equilibria modelling of both metabasic and metapelitic rocks give consistent results within uncertainties, allowing integration of results obtained for both rock types. In combination, the calculations for both metabasic and metapelitic rocks allows an updated and more precisely constrained metamorphic field gradient for Val Strona di Omegna to be defined. The new field gradient has a slightly lower dP/dT which is in better agreement with the onset of crustal thinning of the Adriatic margin during the Permian inferred in recent studies.  相似文献   

Single subduction zone for the generation of Devonian ophiolites and high‐P metamorphic belts of the Variscan Orogen (NW Iberia)     

Rubn Díez Fernndez  Ricardo Arenas  Sonia Snchez Martínez  Irene Novo‐Fernndez  Richard Albert 《地学学报》2020,32(4):239-245

Within the Variscan Orogen, Early Devonian and Late Devonian high‐P belts separated by mid‐Devonian ophiolites can be interpreted as having formed in a single subduction zone. Early Devonian convergence nucleated a Laurussia‐dipping subduction zone from an inherited lithospheric neck (peri‐Gondwanan Cambrian back‐arc). Slab‐retreat induced upper plate extension, mantle incursion and lower plate thermal softening, favouring slab‐detachment within the lower plate and diapiric exhumation of deep‐seated rocks through the overlying mantle up to relaminate the upper plate. Upper plate extension produced mid‐Devonian suprasubduction ocean floor spreading (Devonian ophiolites), while further convergence resulted in plate coupling and intraoceanic ophiolite imbrication. Accretion of the remaining Cambrian ocean heralded Late Devonian subduction of inner sections of Gondwana across the same subduction zone and the underthrusting of mainland Gondwana (culmination of NW Iberian allochthonous pile). Oblique convergence favoured lateral plate sliding, and explained the different lateral positions along Gondwana of terranes separated by Palaeozoic ophiolites.  相似文献   

Geochemical characteristics and sedimentary environment of the Middle Devonian organic-rich shales in the Northwest of Guizhong Depression,Southwest China     

《China Geology》2020,3(4):567-574

In order to figure out the redox conditions and paleo-sedimentary environment of the Middle Devonian shales in the northwest of Guizhong Depression, the trace element analysis was conducted on the Middle Devonian cores (320.35–938.50 m) of the typical shale gas investigation well (GY-1) at a 1.50 m sampling interval through X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). According to the test result, the average values of V/(V+Ni), V/Cr and Ni/Co in Nabiao formation (Fm.) are larger than 0.67, 4.65 and 7.71 respectively, and Nabiao Fm. is rich in biological assemblages such as tabasheer, ammonite, etc. These evidences indicate the rising sea level rose relatively in the sedimentation period of Nabiao Fm. and a deepwater shelf environment, which was favorable for the preservation of organic matters. The V/(V+Ni), V/Cr and Ni/Co in Luofu Fm. and Tangting Fm. are 0.38–0.65, 0.73–4.10 and 3.70–6.72 respectively, indicating that the sea level dropped relatively in their sedimentation period, during which the water bodies became shallow, and the sedimentary environment was a weak oxidizing shallow water shelf environment. In addition, the variation of TOC has a high correlation with the enrichment degree of Ba element, indicating the favorable conditions for the enrichment and preservation of organic matters under an oxygen-deficient environment. Moreover, according to the identification of trace element indexes, the northwest of Guizhong Depression experienced the sedimentary cycle of relative rise to relative fall of sea level from bottom to top in the Middle Devonian sedimentation period. The relative sea level rose to the highest in the sedimentation period of Nabiao Fm., in which the organic-rich shales with stable thickness and high organic content were deposited. Hence, the Nabiao Fm. could be regarded as the favorable exploration target interval in this area.  相似文献   

勉略构造带新元古代洋盆俯冲作用：来自略阳地区纸房沟岩片火山岩锆石U- Pb年龄和Lu- Hf同位素的证据     

徐通  张晓团  焦建刚  张红强  贾力 《地质学报》2020,94(12):3607-3624

纸房沟岩片位于勉略构造带略阳地区。通过细致的岩石学和地球化学研究，将纸房沟岩片内的火山岩分为拉斑玄武岩系列（Ⅰ类）和钙碱性火山岩系列（Ⅱ类）。Ⅰ类火山岩稀土配分曲线左倾，富Na贫P，整体具有N- MORB特点，形成于洋脊构造环境。相比Ⅰ类火山岩，Ⅱ类火山岩具有更高的SiO2(49.02％~61.86％)和K2O(0.32％~1.55％)含量，相对亏损Nb、Ta、P和Ti，形成于陆缘弧构造环境。Ⅱ类火山岩锆石Lu- Hf同位素测试结果显示，εHf(t)值主体为负值，介于-8.01~+0.77，表明其主要为古老地壳物质熔融成因。Ⅱ类火山岩LA- ICP- MS锆石U- Pb测年结果为854±3Ma(MSWD=0.12, n=30)、844±4Ma (MSWD=0.03, n=15)，表明纸房沟岩片火山岩结晶时代为新元古代早中期。综合前人成果认为，纸房沟岩片火山岩为新元古代勉略洋盆俯冲的产物，俯冲作用一直持续到800Ma左右，该俯冲过程很可能是对全球性Rodinia超大陆聚合事件的响应。  相似文献   

东天山博格达晚石炭世双峰式火山岩地球化学特征及意义     

刘亮  李江涛  江辉  杨宇东  何文劲  王莲  王傅佳 《岩石矿物学杂志》2020,39(5):525-538

东天山博格达造山带晚石炭世柳树沟组为一套由玄武岩和流纹岩组成的双峰式火山岩,形成于晚石炭世,其Si O_2含量介于46.18%～46.56%和76.06%～76.25%之间,具有明显的Daly成分间断。其中,玄武岩具富Na贫K特征,Ti O_2、Al_2O_3、Ca O和MgO含量均较高,∑REE为75.54×10~(-6)～80.22×10~(-6),LREE/HREE值为3.00～3.12,以富集Ba、Rb等大离子亲石元素(LILE)和不相容元素(P、K),相对亏损Ti、Ta、Nb等高场强元素(HFSE)和不相容元素(U、Th)为特征;流纹岩Na_2O/K_2O值为0.32～0.36,属低Ti、低Mg类流纹岩,∑REE为520.72×10~(-6)～595.26×10~(-6),LREE/HREE值为5.60～6.53,具有Rb、Th、K、La、Ce、Zr、Hf、Sm等元素的富集以及Ba、U、Ta、Nb、Sr、P和Ti元素的亏损特征。柳树沟组双峰式火山岩形成于大陆裂谷环境,具板内成因特征,玄武岩可能为亏损尖晶石相地幔橄榄岩向石榴石相地幔橄榄岩过渡相较高程度部分熔融的产物,受到地壳物质混染;流纹岩具典型的A型花岗岩的地球化学特征。  相似文献